Primnesin-B1 - Prymnesin-B1

Primnesin-B1
Ismlar
	IUPAC nomi 1 - ((2R, 3S, 4R, 5S, 6R) -6 - ((2R, 2'S, 3'R, 4aS, 4'aR, 6S, 6'S, 7R, 8S, 8aR, 8'S, 8'aS) - 6 '- (2 - ((2R, 4aS, 6S, 7R, 8aR) -6 - ((2S, 4aR, 5aS, 6aR, 7aS, 10R, 11aR, 12aS, 13aR, 15S, 15aS) -10 - (( 1E, 3E, 8E, 10E, 18E) -6-amino-19-chlorononadeca-1,3,8,10,18-pentaen-12,16-diyn-1-yl) -15-hydroxyoctadecahydropyrano [3,2- b] pirano [2,3: 5 ', 6'] pirano [2 ', 3': 5,6] pirano [2,3-f] oksepin-2-yl) -7-metiloktaidropirano [3,2-b] piran-2-yl) -2-gidroksietil) -3 ', 7,8,8'-tetrahidroksiheksadekahidro- [2,2'-bipirano [3,2-b] piran] -6-yl) -3,4,5-trihidroksitetrahidro-2H- piran-2-yl) -3 - (((2R, 3R, 4S, 5R, 6R) -3,4,5-trihidroksi-6- (gidroksimetil) tetrahidro-2H-piran-2-yl) oksi) geksadeka- 13,15-diyne-2,4,6,7,8,9,10-heptaol
Identifikatorlar
3D model (JSmol )	Interaktiv rasm;
PubChem CID	132524595;
	InChI InChI = 1S / C91H132ClNO34 / c1-3-4-5-19-24-48 (95) 72 (103) 76 (107) 73 (104) 50 (97) 37-52 (99) 84 (127-91-) 82 (113) 78 (109) 75 (106) 71 (43-94) 125-91) 53 (100) 39-69-74 (105) 77 (108) 79 (110) 89 (124-69) 90- 81 (112) 80 (111) 88-62 (123-90) 32-31-61 (122-88) 86-55 (102) 40-70-87 (126-86) 51 (98) 36-47 ( 115-70) 35-49 (96) 56-27-28-58-63 (116-56) 34-44 (2) 83 (120-58) 59-29-30-60-85 (121-59) 54 (101) 38-64-66 (118-60) 42-67-68 (119-64) 41-65-57 (117-67) 26-25-46 (114-65) 23-18-15- 17-22-45 (93) 21-16-13-11-9-7-6-8-10-12-14-20-33-92 / h1,9,11,13,15-18,20, 23,33,44-91,94-113H, 8,10,19,21-22,24-32,34-43,93H2,2H3 / b11-9 +, 16-13 +, 17-15 +, 23 -18 +, 33-20 + / t44-, 45?, 46 +, 47 +, 48?, 49?, 50?, 51 +, 52?, 53?, 54 +, 55-, 56-, 57 + , 58 +, 59 +, 60-, 61-, 62 +, 63-, 64-, 65-, 66 +, 67-, 68 +, 69-, 70-, 71-, 72?, 73?, 74 -, 75 +, 76?, 77-, 78 +, 79 +, 80 +, 81-, 82-, 83 +, 84?, 85 +, 86 +, 87 +, 88 +, 89-, 90 +, 91- / m1 / s1;
	Jilmayganlar [H] [C @@] ([C @@] 1 ([H]) [C @@ H] (O) [C @@ H] ([C @ H] (O) [C @] (CC (O) C (O [C @@ H] 2 [C @ H] (O) [C @ H] ([C @@ H] (O) [C @@ H] (CO) O2) O) C (O) CC (O) C (O) C (O) C (O) C (O) CCC # CC # C) ([H]) O1) O) ([C @@ H] ([C @@) H] ([C @] 3 (O [C @] ([C @] (O4) ([H]) [C @ H] (O) C [C @] 5 ([H]) [C @) ” 4 ([H]) [C @@ H] (O) C [C @@] (CC ([C @@] ([H]) (CC [C @] (O [C @@] 6 ([ C @@] (O [C @] 7 ([C @ H] (C8) O) [H]) (CC [C @@] 7 ([H]) O [C @] (C [C @] ([H]) 9O [C @]% 10 (CC [C @@]% 11 (/ C = C / C = C / CC (C / C = C / C = C / C # CCCC # C / C = C / Cl) N) [H]) [H]) ([H]) [C @] 8 ([H]) O [C @] 9 (C [C @@] (O% 11)% 10 [H]) [H]) [H]) [H])% 12 [H]) O [C @@]% 12 (C [C @ H] 6C) [H]) O) ([H]) O5) ([H]) CC% 13) [H]) O) O) O [C @] 3% 13 [H];
Xususiyatlari
Kimyoviy formulalar	C91H132ClNO34
Molyar massa	1819.48 g · mol−1
	Boshqacha ko'rsatilmagan hollar bundan mustasno, ulardagi materiallar uchun ma'lumotlar keltirilgan standart holat (25 ° C [77 ° F], 100 kPa da).
	Infobox ma'lumotnomalari

Primnesin-B1 molekulyar formulali kimyoviy moddadir C
₉₁H
₁₃₂ClNO
₃₄. Bu a'zosi primnesinlar, narvon ramkali polieter klassi fitotoksinlar alga tomonidan qilingan Prymnesium parvum. Baliq uchun zaharli ekanligi ma'lum. Bu "Type-B" primnesin, bu A tipidagi primnesinlarga nisbatan magistral tsikllar soni bo'yicha farq qiladi. primnesin-2.^[1]

Tuzilmalar

Prymnesins-B1 bir nechta konjugat juft va uchli bog'lanishlari, xlor va azot heteroatomlari va bitta shakar bo'lagi bo'lgan katta polieterli polisiklik yadrodan hosil bo'ladi. a-D.-galaktopiranoz.

Shuningdek qarang

Adabiyotlar

^ Rasmussen, Silas Anselm; Meyer, Sebastyan; Andersen, Nikolay Gedsted; Blossom, Xanna Eva; Duus, Jens Ollgaard; Nilsen, Kristian Tuman; Xansen, Per Juel; Larsen, Tomas Ostenfeld (2016-08-23). "Prymneesium parvumdagi narvon ramkali pirimnesin polieterlarining kimyoviy o'zgaruvchanligi". Tabiiy mahsulotlar jurnali. Amerika Kimyo Jamiyati (ACS). 79 (9): 2250–2256. doi:10.1021 / acs.jnatprod.6b00345. ISSN 0163-3864.

[Rasmussen_Meier_Andersen_Blossom_pp._2250–2256-1] Rasmussen, Silas Anselm; Meyer, Sebastyan; Andersen, Nikolay Gedsted; Blossom, Xanna Eva; Duus, Jens Ollgaard; Nilsen, Kristian Tuman; Xansen, Per Juel; Larsen, Tomas Ostenfeld (2016-08-23). "Prymneesium parvumdagi narvon ramkali pirimnesin polieterlarining kimyoviy o'zgaruvchanligi". Tabiiy mahsulotlar jurnali. Amerika Kimyo Jamiyati (ACS). 79 (9): 2250–2256. doi:10.1021 / acs.jnatprod.6b00345. ISSN 0163-3864.

[1]

Ismlar

IUPAC nomi 1 - ((2R, 3S, 4R, 5S, 6R) -6 - ((2R, 2'S, 3'R, 4aS, 4'aR, 6S, 6'S, 7R, 8S, 8aR, 8'S, 8'aS) - 6 '- (2 - ((2R, 4aS, 6S, 7R, 8aR) -6 - ((2S, 4aR, 5aS, 6aR, 7aS, 10R, 11aR, 12aS, 13aR, 15S, 15aS) -10 - (( 1E, 3E, 8E, 10E, 18E) -6-amino-19-chlorononadeca-1,3,8,10,18-pentaen-12,16-diyn-1-yl) -15-hydroxyoctadecahydropyrano [3,2- b] pirano [2,3: 5 ', 6'] pirano [2 ', 3': 5,6] pirano [2,3-f] oksepin-2-yl) -7-metiloktaidropirano [3,2-b] piran-2-yl) -2-gidroksietil) -3 ', 7,8,8'-tetrahidroksiheksadekahidro- [2,2'-bipirano [3,2-b] piran] -6-yl) -3,4,5-trihidroksitetrahidro-2H- piran-2-yl) -3 - (((2R, 3R, 4S, 5R, 6R) -3,4,5-trihidroksi-6- (gidroksimetil) tetrahidro-2H-piran-2-yl) oksi) geksadeka- 13,15-diyne-2,4,6,7,8,9,10-heptaol
Identifikatorlar
3D model (JSmol )	Interaktiv rasm
PubChem CID	132524595
InChI InChI = 1S / C91H132ClNO34 / c1-3-4-5-19-24-48 (95) 72 (103) 76 (107) 73 (104) 50 (97) 37-52 (99) 84 (127-91-) 82 (113) 78 (109) 75 (106) 71 (43-94) 125-91) 53 (100) 39-69-74 (105) 77 (108) 79 (110) 89 (124-69) 90- 81 (112) 80 (111) 88-62 (123-90) 32-31-61 (122-88) 86-55 (102) 40-70-87 (126-86) 51 (98) 36-47 ( 115-70) 35-49 (96) 56-27-28-58-63 (116-56) 34-44 (2) 83 (120-58) 59-29-30-60-85 (121-59) 54 (101) 38-64-66 (118-60) 42-67-68 (119-64) 41-65-57 (117-67) 26-25-46 (114-65) 23-18-15- 17-22-45 (93) 21-16-13-11-9-7-6-8-10-12-14-20-33-92 / h1,9,11,13,15-18,20, 23,33,44-91,94-113H, 8,10,19,21-22,24-32,34-43,93H2,2H3 / b11-9 +, 16-13 +, 17-15 +, 23 -18 +, 33-20 + / t44-, 45?, 46 +, 47 +, 48?, 49?, 50?, 51 +, 52?, 53?, 54 +, 55-, 56-, 57 + , 58 +, 59 +, 60-, 61-, 62 +, 63-, 64-, 65-, 66 +, 67-, 68 +, 69-, 70-, 71-, 72?, 73?, 74 -, 75 +, 76?, 77-, 78 +, 79 +, 80 +, 81-, 82-, 83 +, 84?, 85 +, 86 +, 87 +, 88 +, 89-, 90 +, 91- / m1 / s1
Jilmayganlar [H] [C @@] ([C @@] 1 ([H]) [C @@ H] (O) [C @@ H] ([C @ H] (O) [C @] (CC (O) C (O [C @@ H] 2 [C @ H] (O) [C @ H] ([C @@ H] (O) [C @@ H] (CO) O2) O) C (O) CC (O) C (O) C (O) C (O) C (O) CCC # CC # C) ([H]) O1) O) ([C @@ H] ([C @@) H] ([C @] 3 (O [C @] ([C @] (O4) ([H]) [C @ H] (O) C [C @] 5 ([H]) [C @) ” 4 ([H]) [C @@ H] (O) C [C @@] (CC ([C @@] ([H]) (CC [C @] (O [C @@] 6 ([ C @@] (O [C @] 7 ([C @ H] (C8) O) [H]) (CC [C @@] 7 ([H]) O [C @] (C [C @] ([H]) 9O [C @]% 10 (CC [C @@]% 11 (/ C = C / C = C / CC (C / C = C / C = C / C # CCCC # C / C = C / Cl) N) [H]) [H]) ([H]) [C @] 8 ([H]) O [C @] 9 (C [C @@] (O% 11)% 10 [H]) [H]) [H]) [H])% 12 [H]) O [C @@]% 12 (C [C @ H] 6C) [H]) O) ([H]) O5) ([H]) CC% 13) [H]) O) O) O [C @] 3% 13 [H]
Xususiyatlari
Kimyoviy formulalar	C₉₁H₁₃₂ClNO₃₄
Molyar massa	1819.48 g · mol⁻¹
Boshqacha ko'rsatilmagan hollar bundan mustasno, ulardagi materiallar uchun ma'lumotlar keltirilgan standart holat (25 ° C [77 ° F], 100 kPa da).
Infobox ma'lumotnomalari